COSMOSIL Buckyprep-M
Specialty for Fullerenes / For Metallofullerenes
COSMOSIL Buckyprep-M is a phenothiazinyl group bonded silica based column specifically designed for metallo-fullerene separation. Metallo-fullerenes are retained more strongly than other fullerenes on this column. COSMOSIL Buckyprep-M is also effective for the separation of higher fullerenes and fullerene derivatives.
| COSMOSIL Buckyprep - M | |
|---|---|
| Silica gel | High purity porous spherical silica gel |
| Average particle size | 5 µm |
| Average pore size | approx. 120Å |
| Specific surface area | approx. 300m²/g |
| Stationary phase | Phenothiazinyl |
| End capping treatment | No |
| Carbon content | approx. 13% |
Application 1
Column size: 4.6mmI.D.×250mm; Mobile phase: toluene; Flow rate: 1.0 ml/min.;
Detection: UV 312 nm; Temperature: 30°C
Data courtesy of Professor Hisanori Shinohara (Department of Chemistry, Nagoya University)
Application 2
Column size: 4.6mmI.D.×250mm; Mobile phase: toluene; Flow rate: 1.0 ml/min.;
Detection: UV 312 nm; Temperature: 30°C
Data courtesy of Professor Hisanori Shinohara (Department of Chemistry, Nagoya University)
Usage Information
| Column | 5 µm Buckprep-M | |||
|---|---|---|---|---|
| I.D. (mm) | 2.0 | 4.6 | 10.0 | 20.0 |
| Washing method | Wash with 1,2,4,-trichlorobenzene or other strong solvent to remove adsorbed contaminants. |
|||
| Storage conditions | Wash column, then replace solvent with toluene. Plug tightly and store in a cool, dry place. | |||
| Max. pressure | 20MPa | 15MPa | ||
| Temperature range | The maximum usable temperature is 60°C. However. for regular use, please use at a constant temperature between 20°C and 50°C. | |||
| Solvents usable with Buckyprep Series | ||
|---|---|---|
| Solvent | Features | C60 Solubility (mg/ml) |
| Toluene | General-use solvent for fullerenes. | 3.2 |
| n-Hexane | Weaker eluent than toluene. | 0.046 |
| n-Heptane | ** | |
| Methanol | 0.001 | |
| 2-Propanol | ** | |
| Acetonitrile | Weaker eluent than toluene. | 0.018 |
| Chlorobenzene | Stronger eluent than toluene. | 7 |
| o-Dichlorobenzene | Stronger eluent than chlorobenzene. | 27 |
| 1,2,4-Trichlorobenzene | Strongest commonly-used eluent. Can be used to flush higher fullerenes. | 21.3 |
Fullerene Chromatogram Index
Fullerene Chromatogram Index includes more than 100 chromatograms is available at the website of The Fullerenes, Nanotubes and Graphene Research Society. (Click here to download)
COSMOSIL Application Search
COSMOSIL Application, which includes more than 7,700 applications using COSMOSIL/COSMOCORE columns, is now usable by clicking the link below which is in Nacalai Tesque, Inc. The application is searchable by sample category, sample name, CAS No., column name and particle size
Ordering Information
| Product | Cat.No. | End-Fitting | PKG Size | Price(US$) | |
|---|---|---|---|---|---|
| COSMOSIL Buckyprep-M Packed Column (4.6 mm I.D. x 250 mm) | 04138-71 | Waters type | 1 pkg | 1,980.00 | Buy |
| COSMOSIL Buckyprep-M Packed Column (10.0 mm I.D. x 250 mm) | 04141-11 | Waters type | 1 pkg | 6,447.00 | Buy |
| COSMOSIL Buckyprep-M Packed Column (20.0 mm I.D. x 250 mm) | 04142-01 | Waters type | 1 pkg | 24,043.00 | Buy |
| COSMOSIL Buckyprep-M Packed Column (28.0 mm I.D. x 250 mm) | 05873-01 | Waters type | 1 pkg | 36,584.00 | Buy |
| COSMOSIL Buckyprep-M Guard Column (4.6 mm I.D. x 10 mm) | 04139-61 | Waters type | 1 pkg | 519.00 | Buy |
| COSMOSIL Buckyprep-M Guard Column (10.0 mm I.D. x 20 mm) | 04140-21 | Waters type | 1 pkg | 1,381.00 | Buy |
| COSMOSIL Buckyprep-M Guard Column (20.0 mm I.D. x 50 mm) | 34474-31 | Waters type | 1 pkg | 6,014.00 | Buy |
| COSMOSIL Buckyprep-M Guard Column (28.0 mm I.D. x 50 mm) | 05872-11 | Waters type | 1 pkg | 11,573.00 | Buy |